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Secretary of State Thomas Jefferson 1790-1793
http://www.nndb.com/people/909/000031816/
 
Secretary of State Edmund Randolph 1794-1795
http://www.state.gov/secretary/former/40906.htm
 
Secretary of State Timothy Pickering 1795-1800
http://www.senate.gov/artandhistory/history/common/image/Timothy_Pickering.htm
 
Secretary of State John Marshall 1800-1801
http://usinfo.state.gov/products/pubs/constitution/supreme.htm
 
Secretary of State James Madison 1801-1809
http://memory.loc.gov/ammem/today/mar16.html
 
Secretary of State Robert Smith 1809- 1811
http://www.state.gov/secretary/former/40901.htm
 
Secretary of State James Monroe 1811-1814, 1815-1817
http://www.state.gov/secretary/former/40898.htm
 
Speaker of the House Henry Clay 1811-1814 1815-1820 1823-1825. Senator from Kentucky, Secretary of State 1825-1829, Presidential Candidate 1824
http://en.wikipedia.org/wiki/Henry_Clay
 
James Monroe Secretary of State under Madison
http://www.army.mil/cmh-pg/books/sw-sa/Monroe.htm
 
Secretary of State John Quincy Adams 1817-1825
http://www.state.gov/secretary/former/40897.htm
 
Secretary of State James Monroe under James Madison
http://www.johnhorse.com/trail/01/b/03.htm
 
Secretary of State Henry Clay
http://www.americaslibrary.gov/jb/reform/jb_reform_claydied_1_e.html
 
Secretary of State Henry Clay 1825-1829
http://www.state.gov/secretary/former/40896.htm
 
Monroe Doctrine coins showing President Monroe and Secretary of State Adams
http://www.usgoldcoins.com/coins/Silver%20Halves/monroe_half.htm
 
1817 President James Monroe, Secretary of State John Quincy Adams, Attorney General William Wirt, Secretary of War John Calhoun, and Secretary of the Navy Samuel L. Southard.
http://www.aoc.gov/cc/art/cox_corr/g_exp/monroe.cfm?closeup=1
 
Secretary of State Martin Van Buren 1829-1831
http://www.state.gov/secretary/former/40895.htm
 
Secretary of State Edward Livingston 1831-1833
http://www.state.gov/secretary/former/40894.htm
 
Secretary of State Louis McLane 1833-1834
http://bioguide.congress.gov/scripts/bibdisplay.pl?index=M000535
 
Secretary of State John Forsyth 1834-1841
http://www.state.gov/secretary/former/40892.htm
 
Daniel Webster Secretary of State 1841
http://www.historyplace.com/specials/calendar/docs-pix/jan-webster.htm
 
Secretary of State Daniel Webster 1841-1843
http://www.state.gov/secretary/former/40885.htm
 
Secretary of State Abel P. Upshur 1843-1844
http://www.state.gov/secretary/former/40890.htm
 
Secretary of State John C. Calhoun 1844-1845
http://www.state.gov/secretary/former/40889.htm
 
Secretary of State James Buchanan 1845-1849
http://www.state.gov/secretary/former/40888.htm
 
1844 Polk elected. Presidential Candidate former Secretary of State and former Speaker Henry Clay had 105 votes vs 170 with running mate Senator Theodore Frelinghuysen
http://www.historycooperative.org/journals/jah/90.1/kornblith.html
 
Secretary of State John Clayton 1849-1850
http://bioguide.congress.gov/scripts/biodisplay.pl?index=C000496
 
Secretary of State Daniel Webster 1850-1852
http://www.historyplace.com/specials/calendar/docs-pix/jan-webster.htm
 
1848 Taylor elected. Presidential Candidate Senetor Lewis Cass had 127 votes vs 163 with running mate William O. Butler. Cass became Secretary of State in 1857.
http://en.wikipedia.org/wiki/Lewis_Cass
 
Secretary of State Edward Everett 1852-1853
http://dosfan.lib.uic.edu/ERC/secretaries/eeverett.htm
 
Secretary of State William L. Marcy 1853-1857
http://www.army.mil/cmh-pg/books/sw-sa/Marcy.htm
 
Secretary of State Lewis Cass 1857-1860
http://www.army.mil/cmh-pg/books/sw-sa/Cass.htm
 
Secretary of State James Buchanan 1845-1849
http://dosfan.lib.uic.edu/ERC/secretaries/jbuchanan.htm
 
Secretary of State Jeremiah S. Black 1860-1861
http://www.salisburypa.com/salisburyschool2.html
 
Secretary of State William H. Seward 1861-1866
http://www.rootsweb.com/~nycayuga/ugrr/pg1.html
 
1860 Third party Presidential Candidate Senator John Bell received 39 votes with running mate former Massachusetts Senator and Governor and Secretary of State Edward Everett
http://www.army.mil/cmh-pg/books/sw-sa/Bell.htm
 
Secretary of State William H. Seward 1866-1869
http://www.sitnews.us/JuneAllen/Seward/032706_william_seward.html
 
Secretary of State Elihu B. Washburne 1869-1869
http://www.mrlincolnswhitehouse.org/photo_credits_content.asp?photoID=1573&subjectID=&ID=
 
Secretary of State Hamilton Fish 1869-1877
http://www.forgotten-ny.com/STREET%20SCENES/Facades/facade.html
 
Speaker of the House James G. Blaine 1869-1875, Senator from Maine 1875-1882, Secretary of State twice 1881 1889-1892
http://www.jewishworldreview.com/0104/tobin_2004_01_04.php3
 
Secretary of State William M. Evarts 1877-1881
http://bioguide.congress.gov/scripts/biodisplay.pl?index=E000262
 
Secretary of State James G. Blaine 1881-1881
http://www.heritage.nf.ca/law/jamesblaine.html
 
Secretary of State Frederick T. Frelinghuysen 1881-1885
http://www.dxhansen.com/SSHansen-p/p13.htm
 
Secretary of State Thomas F. Bayard, Sr. 1885-1889
http://www.library.georgetown.edu/dept/speccoll/fl/f63%7D1.htm
 
1884 Cleveland elected. Presidential Candidate former Speaker and Senator and Secretary of State James G. Blaine had 182 votes vs 219 with running mate Senator John A. Logan
http://en.wikipedia.org/wiki/Mugwump
 
Secretary of State James G. Blaine 1889-1892
http://www.mpbn.net/homestom/timelines/bios/blaine.html
 
Secretary of State John W. Foster 1892-1893
http://dosfan.lib.uic.edu/ERC/secretaries/jfoster.htm
 
Secretary of State Walter Q. Gresham 1893-1895
http://dosfan.lib.uic.edu/ERC/secretaries/wgresham.htm
 
Secretary of State Richard Olney 1895-1897
http://www.state.gov/secretary/former/40855.htm
 
Secretary of State John Sherman 1897-1898
http://waysandmeans.house.gov/legacy/portraits/1789-1898/sherman.htm
 
Secretary of State William R. Day 1898-1898
http://en.wikipedia.org/wiki/William_R._Day
 
Secretary of State John Hay 1898-1905
http://ublib.buffalo.edu/libraries/exhibits/panam/johnhay.html
 
Secretary of State Elihu Root 1905-1909
http://www.army.mil/cmh-pg/books/cg&csa/CG-Intro-II.htm
 
Secretary of State Robert Bacon 1909-1909
http://www.answers.com/topic/robert-bacon
 
Secretary of State Philander C. Knox 1909-1913
http://dosfan.lib.uic.edu/ERC/secretaries/pknox.htm
 
Secretary of State William Jennings Bryan 1913-1915
http://www.americaslibrary.gov/aa/bryan/aa_bryan_subj_e.html
 
Secretary of State Robert Lansing 1915-1920
http://www.gwpda.org/photos/heads.htm
 
1916 Wilson re-elected. Presidential Candidate former NY Governor and former Supreme Court Justice Charles Evans Hughes had 254 votes vs 277 with running mate Charles W. Fairbanks. Huges later became Secretary of State (1921) and Chief Justice (1930). Charles Fairbanks was a former Vice President under Theodore Roosevelt
http://c250.columbia.edu/c250_celebrates/remarkable_columbians/charles_hughes.html